传统的铱配合物大多采用的环金属配体是苯基吡啶衍生物。南京大学化学化工学院郑佑轩课题组最近通过在在咔唑一号位上引入吡啶开发了新型铱配合物,不仅有利于载流子在发光层的注入和传输,并且能有效抑制咔唑N上苯基自由弛豫引起的非辐射跃迁,其器件具有高达32.2%的外量子效率和低效率滚降。
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