广东工业大学李成超教授基于插层化学策略,在MoO3层间引入有机分子铋硫醇(DMcT)。DMcT分子的插入不仅扩展了Na+扩散通道提升钠离子嵌入/脱出动力学,而且作为层间柱撑分子使得充放电过程中的层结构更加稳定。更重要的是, DMcT分子特有的共轭双键有效地屏蔽了Na+与MoO3主体之间的静电相互作用,进一步改善了Na+的插入/脱出动力学。
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